The Irish bookmaker will also refund all losing stakes as a free bet, making this exclusive offer effectively a risk-free investment.
Simply back the five teams to win at the normal price displayed on site, and if your bet wins, your account will be topped up as per the terms and conditions set out here.
Chelsea travel to Maribor looking to replicate the same dominant performance which earned them a 6-0 win at Stamford Bridge last month.
Jose Mourinho’s men are the heavy favourites to secure victory at odds of around 1/3 with most bookmakers.
Manchester City, meanwhile, are facing a simply must-win game against CSKA Moscow at Etihad Stadium.
Despite their stuttering form in Europe, City are still the heavy favourites to win at odds of around 3/10.
Bundesliga champions Bayern Munich host Roma in Germany and are 1/4 favourites to beat their Italian opponents.
Barcelona travel to Ajax as the 4/11 favourites to beat the Dutch side at the Amsterdam Arena.
Ligue 1 giants Paris Saint-Germain complete the line-up, with the French side 1/4 to beat Apoel Nicosia.
Backing all five favourites to win their games on Tuesday would get you odds of around 4/1 with most bookmakers, so Paddy Power’s price boost to 10/1 is sure to tempt plenty of fans into a flutter ahead of kick-off on Wednesday night.
MORE: Man United latest news
MORE: Arsenal latest news
MORE: Chelsea latest news
MORE: Liverpool latest news